New publication: "Temperature dependent ambipolar charge carrier mobility in large crystal hybrid halide perovskite thin films", Alexander Biewald, Nadja Giesbrecht, Thomas Bein, Pablo Docampo, Achin Hartschuh and Richard Ciesielski

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New publication: "Tip-Enhanced Spectroscopy and Imaging of Carbon Nanomaterials", by Ado Jorio, Luiz Gustavo Cançado, Sebastian Heeg, Lukas Novotny and Achim Hartschuh (Dedicated to the Memory of Professor Mildred S Dresselhaus)

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New publication: "Freely Suspended, van der Waals Bound Organic Nanometer‐Thin Functional Films: Mechanical and Electronic Characterization", Lilian S. Schaffroth, Jakob Lenz, Veit Giegold, Maximilian Kögl, Achim Hartschuh and R. Thomas Weitz

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New Publication: "Efficient Hotspot Switching in Plasmonic Nanoantennas using Phase-shaped Laser Pulses controlled by Neural Networks", Alberto Comin and Achim Hartschuh,

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Universitaet Muenchen
Department Chemie
Butenandtstr. 5-11 (Haus E, Gerhard-Ertl-Gebaeude)
81377 Muenchen

Phone: +49 89 2180 77515
Mail: Prof. A. Hartschuh
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Tip-enhanced near-field optical microscopy

The technique we use relies on the locally enhanced optical fields close to a laser illuminated, sharp metal tip. The sample is raster scanned below the tip which can act as a highly confined excitation source providing a considerable signal enhancement and spectroscopic images at very high spatial resolution.

A. Hartschuh, Angew. Chemie 47, 8178 (2008)

Our experimental setup is based on an inverted optical microscope with an x, y scan stage for raster scanning a transparent sample. The excitation is provided by a HeNe laser operating at 632.8 nm that is reflected by a dichroic beam splitter and focused by a high numerical aperture objective (1.4 NA) on the sample surface.

A sharp gold tip is positioned near the focus of the beam and maintained above the sample surface at a distance of ~1-2 nm by means of a sensitive shear-force feedback mechanism. The gold tips with a radius of 10-15 nm are produced by electrochemical etching.

Both Raman scattered light and luminescence are collected with the same objective, transmitted by the beam splitter and separated by a long pass filter. The signal is then detected either by a combination of a spectrograph and a charged coupled device (CCD) or by avalanche photodiodes (APDs).

Tip-enhanced near-field microscopy allows for optical imaging with a spatial resolution below 20 nm and spectroscopy on a nanometer scale.



TENOM on CdSe nanowires

Tip-enhanced photoluminescence (PL) and Raman scattering images of single CdSe nanowires were obtained with a spatial resolution of less than 20 nm. They show that the optical properties of the CdSe NWs vary significantly within a few nanometers leading to strong spatial fluctuations in both PL intensities and energies. Energy gradients of up to 1 meV/nm could be observed. In addition, we showed that two bundled nanowires featuring different band gaps due to different diameters could be spatially resolved by their optical properties.

TENOM is found to be highly suited to study the optical properties of CdSe NWs on nanometer lenghtscales.



Visualizing the Local Optical Response of Semiconducting Carbon Nanotubes to DNA-Wrapping

We studied the local optical response of semiconducting single-walled carbon nanotubes to wrapping by DNA segments using high resolution tip-enhanced near-field microscopy. Photoluminescence (PL) near-field images of single nanotubes reveal large DNA-wrapping induced redshifts of the exciton energy that are two times higher than indicated by spatially averaging confocal microscopy. Near-field PL spectra taken along nanotubes feature two distinct PL bands resulting from DNA-wrapped and un-wrapped nanotube segments. The transition between the two energy levels occurs on a length scale smaller than our spatial resolution of about 15 nm.

H. Qian et al. Nano Lett. 8, 2706 (2008)


2D photoluminescence maps taken at two different positions of a single(6,4) nanotube (a,d) as a function of tip sample distance. The difference between the two emission energies, marked by two white dashed lines, is due to DNA-wrapping.